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Matchday 2
21st · Home
20:00Tue, 13 Oct 2026
27th · Away
Venue Estadio de la CeramicaReferee Daniel SiebertWatch (UK) TNT Sports

Villarreal v Napoli: Champions League preview, predicted line-ups and team news

Both sides lost their Champions League openers and both need points at the Estadio de la Ceramica. Napoli are without five players, including Anguissa and Buongiorno.

Published
Mon 12 Oct, 09:45
Updated
Mon 12 Oct, 22:28

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Villarreal v Napoli: both sides need a first point

Villarreal and Napoli both lost their Champions League league-stage openers, and one of them will leave the Estadio de la Ceramica on Tuesday with a second straight defeat.

The hosts went down 3-2 at Borussia Dortmund on 8 September. Napoli lost 1-0 at home to Arsenal the following night. Neither side has a point, and with the league stage only eight games long, there is little room for a slow start.

Villarreal have the better argument. They scored twice away from home and were the more dangerous side in their opener. Napoli did not.

BET FOOTBALL
VillarrealVillarreal
VS
NapoliNapoli
Tue 13 Oct, 20:00•Estadio de la Ceramica

How they got here

Villarreal lost in Dortmund despite scoring twice, in the 46th and 61st minutes. All three goals they conceded came between the 76th and 90th minutes. Their recent-form data shows 13 shots per game, six of them on target, and an expected-goals figure of 1.34 for, against 2.83 against. They were lucky to lose only by one.

Napoli were beaten at home by Arsenal. The only goal came between the 61st and 75th minutes. They had 42% of the ball and five shots, three of them on target, and failed to score. That is the thinnest attacking return in the competition so far from a side of their standing.

There is no aggregate to protect. This is a single league-stage fixture, and the points count the same whoever collects them.

Rotation and selection

Rotation is not a major factor here. With both sides pointless after one game, expect each to field its strongest available XI.

Napoli have little choice anyway. Their injury list removes several regular options, so the visitors are more likely to be reshaped by absentees than by choice. Villarreal lose only one player from the supplied list and can keep the 4-2-3-1 they used in Germany.

Last 6 · most recent left
VillarrealVillarreal
LW0 D0 L1
NapoliNapoli
LW0 D0 L1
Champions League · season 2026 · UEFA Champions LeagueLive snapshot
#TeamPGDPts
20FenerbahçeFenerbahçe101
21VillarrealVillarreal1-10
22LilleLille1-10
23Slavia PrahaSlavia Praha1-10
24Club Brugge KVClub Brugge KV1-10
25InterInter1-10
26Atletico MadridAtletico Madrid1-10
27NapoliNapoli1-10
28Lask LinzLask Linz1-10
Champions League
Last 5 meetings · most recent first
  1. 17 Dec 22Napoli2–3VillarrealVillarreal
  2. 25 Feb 16Napoli1–1VillarrealDraw
  3. 18 Feb 16Villarreal1–0NapoliVillarreal
  4. 7 Dec 11Villarreal0–2NapoliNapoli
  5. 27 Sept 11Napoli2–0VillarrealNapoli
Home wins
2
Draws
1
Away wins
2
Goals · H / A
6 / 6

Predicted line-ups for Villarreal v Napoli

Villarreal: Luiz Junior; Foyth, Mourino, Logan Costa, Carlos Romero; Comesana, Gueye; Pepe, Moleiro, Ayoze Perez; Mikautadze

Napoli: Meret; Di Lorenzo, Beukema, Rafa Marin, Spinazzola; Lobotka, McTominay, De Bruyne; Politano, Hojlund, David Neres

Where to watch Villarreal v Napoli: TV and online streams

Villarreal v Napoli kicks off at 20:00 BST on Tuesday 13 October at the Estadio de la Ceramica. The match is shown on TNT Sports where selected. The exact channel has not been confirmed and this page will be updated closer to kick-off.

This is a single league-stage fixture, not a two-legged tie. There is no extra time in the league phase. The result after 90 minutes stands.

Stats for Villarreal v Napoli

  • Napoli won both Champions League meetings in 2011, 2-0 at home on 27 September and 2-0 at Villarreal on 7 December.
  • The sides met in the Europa League last 16 in February 2016: Villarreal won 1-0 at home, then drew 1-1 in Naples.
  • The last meeting was a friendly on 17 December 2022 at the Stadio Diego Armando Maradona. Villarreal won 3-2.
  • Across five meetings there have been two wins each and one draw, at an average of 2.4 goals per game.
TIP 01

Correct Score: 2-1

Villarreal scored twice in Dortmund and conceded three, and the H2H average of 2.4 goals fits a narrow scoreline. Napoli blanked at home against Arsenal, but they are good enough to find one in Spain. Two-one is the pick. It is a long-shot price, so size the stake accordingly.

Best Price
8/1
Place bet
Odds correct at time of publish.
TIP 02

Over 2.5 Goals: Over

Villarreal's opener produced five goals, and their expected goals against was 2.83. Napoli's defence is short of Anguissa and Buongiorno. Only one of the five previous meetings with Napoli went over 2.5, so this is not a certainty. At 3/5 the price is fair.

Best Price
3/5
Place bet
Odds correct at time of publish.
TIP 03

Both Teams to Score: Yes

Villarreal conceded three at Dortmund and have not kept a clean sheet. Napoli's lone attacking return was a blank, which is the risk. With Hojlund and De Bruyne in the XI they should still score once. The bet is 8/15.

Best Price
9/17
Place bet
Odds correct at time of publish.
TIP 04

Anytime Goalscorer: Gerard Moreno

Villarreal scored twice in Dortmund and will look to the front line for goals again. Moreno is an experienced finisher and a regular source of chances in this attack. He may start on the bench, which is the risk to this pick. Mikautadze is the alternative.

Best Price
9/5
Place bet
Odds correct at time of publish.
TIP 05

Double Chance: Home or Draw

Napoli have scored no goals this season and are missing five players. Villarreal have home advantage and the higher expected-goals return of the two. Only a Napoli win beats this selection, at a price of 4/11.

Best Price
5/13
Place bet
Odds correct at time of publish.

Build the Villarreal v Napoli bet

BetFootball Builder · 3 LegsCombined Price Below
Home Win
Match Result
11/10

Villarreal are the anchor. A home win at 11/10 sits comfortably with goals in the game, because the hosts will need to score more than once to beat a Napoli side that is short in defence.

Over
Over 2.5 Goals
3/5

Over 2.5 pairs with the home win because a 2-1 or 3-1 result lands both legs. Villarreal's defending late in games keeps Napoli in the match and the total high.

Gerard Moreno
Anytime Goalscorer
9/5

A Villarreal goalscorer leg completes the builder. It rides on the same home-win scenario without duplicating the result or total, and Moreno is the likeliest finisher in a front line that has scored twice.

Combined Price
143/17
Stake£10.00
Returns£94.08
Profit+£84.08
Build at bet365
Builder goes to bet365 · 18+ · GambleAware
Odds correct at time of publish.